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Merck, 673293-1G, Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

Size:1 g, Cp*RuCl(PPh₃)₂, Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
Available Catalog Numbers
673293-1G673293-250MG
Catalog Number: 673293-1G
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Category
Photocatalysts
Pack Size1 g
TagsCatalystsChemistry & BiochemicalsTransition Metal Catalysts
CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & BioproductionMerck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification
Manufacturer's Pagewww.sigmaaldrich.com/US/en/product/ALDRICH/673293
Description
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a versatile catalyst for regioselective 3+2 cycloaddition of azides and alkynes (RuAAC), producing 1,5-disubstituted triazoles. Click here for more information.
Application
Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
Versatile catalyst for living radical polymerization
Specifications

General

UNSPSC Code12161600
PubChem Substance ID24885155
NACRESNA.22
Web Name Suffix Overridesolid
MDL numberMFCD09038426
SMILES stringCl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
InChI keyKLXKSZDVKAWYRT-UHFFFAOYSA-M
formsolid
reaction suitabilitycore: ruthenium
Quality Level100
greener alternative product characteristicsCatalysisLearn more about the Principles of Green Chemistry.
sustainabilityGreener Alternative Product
mp128 °C (D)
greener alternative categoryAligned
storage temp.2-8°C