Merck, 688983-1KG, Ethyl acetoacetate
Size:1 kg, Acetoacetic ester, Arxada quality, ≥99.0% (GC)
Available Catalog Numbers
Catalog Number: 688983-1KG
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Category
Pack Size1 kg
Description
Application
Ethyl acetoacetate can undergo:
Transesterification with primary and secondary alcohols in the presence of boric acid.
Microbial reduction to form (S)-ethyl 3-hydroxybutyrate.
C-acylation by acid chlorides in the presence of magnesium chloride and pyridine.
Asymmetric biphasic catalytic hydrogenation in the presence of a water-soluble ruthenium-BINAP complex.
Ethyl acetoacetate can undergo:
Transesterification with primary and secondary alcohols in the presence of boric acid.
Microbial reduction to form (S)-ethyl 3-hydroxybutyrate.
C-acylation by acid chlorides in the presence of magnesium chloride and pyridine.
Asymmetric biphasic catalytic hydrogenation in the presence of a water-soluble ruthenium-BINAP complex.
Specifications
General
| UNSPSC Code | 12352100 |
|---|---|
| NACRES | NA.22 |
| PubChem Substance ID | 329761207 |
| EC Number | 205-516-1 |
| Beilstein/REAXYS Number | 385838 |
| MDL number | MFCD00009199 |
| InChI key | XYIBRDXRRQCHLP-UHFFFAOYSA-N |
| InChI | 1S/C6H10O3/c1-3-9-6(8)4-5(2)7/h3-4H2,1-2H3 |
| SMILES string | CCOC(=O)CC(C)=O |
| vapor density | 4.48 (vs air) |
| vapor pressure | 1 mmHg ( 28.5 °C) |
| assay | ≥99.0% (GC) |
| form | liquid |
| autoignition temp. | 580 °F |
| quality | Arxada quality |
| expl. lim. | 9.5 % |
| manufacturer/tradename | Arxada AG |
| impurities | ≤0.05% water |
| color | APHA: ≤15 |
| bp | 180 °C |
| mp | −43 °C (lit.) |
| solubility | water: soluble 130 g/L at 20 °C |
| density | 1.029 g/mL at 20 °C (lit.) |
| Quality Level | 200 |
