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Merck, 912948-500MG, Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

Size:500 mg
Available Catalog Numbers
912948-500MG912948-50MG
Catalog Number: 912948-500MG
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Category
Photocatalysts
Pack Size500 mg
TagsCatalystsChemistry & BiochemicalsPhotocatalysts
CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & BioproductionMerck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification
Manufacturer's Pagewww.sigmaaldrich.com/US/en/product/ALDRICH/912948
Description
Application
Ir[FCF₃(CF₃)ppy]₂(dtbbpy)PF₆ is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Other Notes
Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis
Specifications

General

MDL numberMFCD32851671
UNSPSC Code12352101
Web Name Suffix Overridepowder
NACRESNA.22
InChI keyHNVAXJZTSVKZHB-UHFFFAOYSA-N
SMILES string[Ir+].FC(F)(F)c5cnc(cc5)c6c(cc(cc6)C(F)(F)F)F.FC(F)(F)c3cnc(cc3)c4c(cc(cc4)C(F)(F)F)F.F[P-](F)(F)(F)(F)F.n1c(cc(cc1)C(C)(C)C)c2nccc(c2)C(C)(C)C
formpowder
reaction suitabilityreaction type: Photocatalysis
mp378 °C
Quality Level100