Merck, C409-100G, (1R,3S)-(+)-Camphoric acid
Size:100 g, (+)-Camphoric acid, (1R, 3S)-1, 2, 2-Trimethyl-1, 3-cyclopentanedicarboxylic acid, 99%
Available Catalog Numbers
Catalog Number: C409-100G
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Category
Pack Size100 g
Description
General description
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
Application
(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
Application
(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.
Specifications
General
| UNSPSC Code | 51113400 |
|---|---|
| NACRES | NA.22 |
| PubChem Substance ID | 24892576 |
| EC Number | 204-715-0 |
| Beilstein/REAXYS Number | 2050204 |
| MDL number | MFCD00001375 |
| InChI key | LSPHULWDVZXLIL-LDWIPMOCSA-N |
| InChI | 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1 |
| SMILES string | CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O |
| assay | 99% |
| form | powder |
| optical activity | [α]20/D 46°, c = 1 in ethanol |
| mp | 183-186 °C (lit.) |
